Directions:
a) list and define all vocabulary from the chapter
b) type at least 4 sample problems with step-by-step directions of how to solve the problem; list the correct answers (if your chapter doesn't have math, there are still problems and concepts we learned.)
c) link at least 3 websites for additional resources to help with studying
d) develop your own LEQ questions for the section - what did you think were the key points we learned?
e) Once your page is done, visit 4 other chapters and answer their LEQ's. (This can be done on a separate piece of paper.)

Vocab-


  • Pressure- force / area
-units of pressure:
- 1 atm- atmospheres = 760 mmHg = 760 Torr
- 1 atm = 101,325 Pa (pascal) = 101.325 KPa (kilopascal)
  • Boyle's Law- (P1)(V1) = (P2)(V2)
    • constant temperature, constant amount of gas
    • pressure changes inversely to volume
  • Charles' Law- V1/T1 = V2/T2
    • Temperature and volume increase proportionally
    • Temperature MUSTbe in Kelvin
      • T(k) = T(Celsius) + 273.15
  • Ideal Gas Law- PV= nRT
    • R is the gas constant - used when discussing a SINGLE gas in a NON-CHANGING environment
      • R = PV/ nT= (1 atm)(22.414 L) / (1 mol)(273.15 K)
      • R= (0.082057 x atm) / (mol x K) or (8.314 x KPa)/ (mol x K)
  • STP- Standard temperature and pressure= 0 degrees Celsius and 1 atm of pressure
    • Experiments show that at STP, 1 mol of an Ideal Gas occupies 22.414 L
  • Combined Gas Law- (P1)(V1) / T1 = (P2)(V2)/ T2
    • happens when n and R are constant
  • Dalton's Law of Partial Pressure = Ptotal= Pa+ Pb
    • V and T are CONSTANT
    • Pa = (nA)(R)(T) / V and Pb = (nB)(R)(T) / V
    • Mole Fraction (X) is the percent of each gas pressure present in the total.
      • XA= nA / (nA + nB) and XB= nB / (nA + nB)
  • Graham's Law= Rate 1 / Rate 2 = Sqr root of (M2 / M1)
    • Rate 1 = faster, lighter gas
    • Rate 2 = slower, heavier gas
    • Comparing two or more speeds of gases.

Helpful LEQ's:

  • When do you use each Gas Law?
  • What are the formulas of each gas law?
  • What are the units of pressure?
  • What are the different relationships between pressure and volume in the different gas laws?



Practice Problems:

  • Boyle's:
    • A sample of chlorine gas occupies a volume of 946 mL at a pressure of 726 mmHg. What is the pressure of the gas (in mmHg) if the volume is reduced at a constant temperature to 154 mL?
    • (726)(946)= P2(154)
      • Divide each side by 154 to find the figure for P2
      • the answer will be 4460 mL
  • Charles' :
    • A sample of carbon monoxide gas occupies 3.20 L at 125 degrees Celsius. At what temperature will the gas occupy a volume of 1.54 L if the pressure remains the same?
      • Change the temperature to kelvin: 125 + 273.15
      • T2 = V2(T1) / V1 = (1.54)(398.15) / 3.20 = 191.6 Kelvin
  • Ideal Gas Laws:
    • A Balloon contains 2.00 g of He at a pressure of 105 kPa and a temperature of 300 Kelvin. What is the volume of the balloon?
      • PV = nRT therefore V= (nRT) / P
      • Find the moles of He in 2.00 g
      • plug it all in
        • V= (.5)(300)(8.314) / 105
        • V= 11.9 L
  • Combined:
    • a 7.00L Sample of argon gas at 420 Kelvin exerts a pressure of 625 kPa. If the gas is compressed to 1.25 L and the temperature is lowered to 350 Kelvin, what will be the new pressure?
      • P1(V1) / T1 = P2(V2) / T2
      • 625(7.00L) / 420 K = P2(1.25) / 350 K
      • Cross multiply the fractions and solve for P2
      • P2= 2920 kPa
  • Dalton's:
    • A mixture of 1.00 g of H2 and 1.00 g of He is placed in a 1.00l container at 27 degrees C. calculate the partial pressure of each gas and the total pressure.
      • PV= nRT therefore P= nRT / V
      • Convert temp to Kelvin
      • Find the moles of H2, plug it all in:
      • (0.48)(0.0821)(300.15) / 1L = 12.07 atm H2
      • Do the same math for He:
      • (0.25)(0.0821)(300.15) / 1L = 6.16 atm He
      • Add the pressurestogether to get the Ptotal: 18.23 atm
  • Graham's Law:
  • What is the molecular weight of a gas which diffuses 1/50 as fast as hydrogen?
  • Rate1/ rate 2 = sqr root of M2 / M1
  • 1/50 = sqr root of 2.02 / x
  • Sqr both sides, cross multiply
  • X= 5050 g/mol






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